Carbon black nanoparticles film electrode prepared by using substrate-induced deposition approach
Identifieur interne : 006B87 ( Main/Repository ); précédent : 006B86; suivant : 006B88Carbon black nanoparticles film electrode prepared by using substrate-induced deposition approach
Auteurs : RBID : Pascal:09-0013575Descripteurs français
- Pascal (Inist)
- Electrode carbone, Noir carbone, Nanoparticule, Electrode couche mince, Oxyde d'indium, Oxyde d'étain, Verre, Fonctionnalisation, Microscopie électronique balayage, Spectrométrie IR, Voltammétrie cyclique, Transfert électron, Système redox, Acétonitrile, Méthode électrochimique, Evaluation performance, Acide ascorbique, Voltammétrie redissolution anodique, Onde carrée, Milieu acide, Ampérométrie, Peroxyde d'hydrogène, Injection en écoulement, Reproductibilité, Dispositif électrochimique.
- Wicri :
- concept : Verre.
English descriptors
- KwdEn :
- Acetonitrile, Acid medium, Amperometry, Anodic stripping voltammetry, Ascorbic acid, Carbon black, Carbon electrode, Cyclic voltammetry, Electrochemical device, Electrochemical method, Electron transfer, Flow injection, Functionalization, Glass, Hydrogen peroxide, Indium oxide, Infrared spectrometry, Nanoparticle, Performance evaluation, Redox system, Reproducibility, Scanning electron microscopy, Square wave, Thin layer electrode, Tin oxide.
Abstract
A new type of carbon film electrode, composed of a thin layer of tightly packed carbon black (CB) nanoparticles deposited onto a gelatin-covered indium tin oxide/glass support using the surface-induced deposition (SID) approach, is presented. Some parameters of the novel SID method were optimized and the surface image and functionalization of the investigated carbon black film electrode (CBFE) was inspected by employing scanning electron microscopy and infrared spectroscopy. A cyclic voltammetry (CV) study was conducted in which the electron-transfer kinetics and CBFE interfacial characteristics were evaluated employing several selected reference redox systems, such as [Ru(NH3)613+/2+, [Fe(CN)6]3-/4- and Fe3+/2+ in aqueous, and ferrocene/ferrocenium in acetonitrile media. CV recordings were also performed in order to compare the electrochemical behavior of the CBFE with that of some well-known and established bare carbon-based electrodes. In order to confirm the validity of the CB film preparation method, the electroanalytical performance of the proposed CBFE was examined by carrying out linear sweep voltammetry of ascorbic acid (AA), anodic stripping square-wave voltammetry ofCu(II) in acidic medium, and amperometric measurements of hydrogen peroxide under flow injection conditions. The sensing characteristics of the novel carbon film electrode, demonstrated in this preliminary study, comprise: (i) a wide working potential window ranging from +1.0 to -1.3V (depending on the solution pH), (ii) a wide applicable pH range (at least from 2 to 12), (iii) low voltammetric background (<5 μA cm-2),(iv) a satisfactory linear voltammetric and amperometric response (r2 > 0.99)to various analytes, (v) good reproducibility (for example, r.s.d. of 2% in amperometric detection of H2O2 and r.s.d. of 8.5% for electrode-to-electrode CV runs), and (vi) stable and fast current response (at least 100 CV runs with negligible change in CV response). The main advantages of the proposed CBFE originate from the unique CB film formation procedure that enables fast, simple, inexpensive and non-toxic CBFE preparation, which can find application in advanced electrochemical devices and is suitable for mass production.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Carbon black nanoparticles film electrode prepared by using substrate-induced deposition approach</title><author><name>IRENA GRABEC SUEGL</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>National Institute of Chemistry, P.O. Box 660</s1><s2>1001 Ljubljana</s2><s3>SVN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Slovénie</country><wicri:noRegion>1001 Ljubljana</wicri:noRegion></affiliation></author><author><name sortKey="Bele, Marjan" uniqKey="Bele M">Marjan Bele</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>National Institute of Chemistry, P.O. Box 660</s1><s2>1001 Ljubljana</s2><s3>SVN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Slovénie</country><wicri:noRegion>1001 Ljubljana</wicri:noRegion></affiliation></author><author><name sortKey="Ogoreuc, Bozidar" uniqKey="Ogoreuc B">Bozidar Ogoreuc</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>National Institute of Chemistry, P.O. Box 660</s1><s2>1001 Ljubljana</s2><s3>SVN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Slovénie</country><wicri:noRegion>1001 Ljubljana</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">09-0013575</idno><date when="2008">2008</date><idno type="stanalyst">PASCAL 09-0013575 INIST</idno><idno type="RBID">Pascal:09-0013575</idno><idno type="wicri:Area/Main/Corpus">005E82</idno><idno type="wicri:Area/Main/Repository">006B87</idno></publicationStmt><seriesStmt><idno type="ISSN">0003-2670</idno><title level="j" type="abbreviated">Anal. chim. acta</title><title level="j" type="main">Analytica chimica acta</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acetonitrile</term><term>Acid medium</term><term>Amperometry</term><term>Anodic stripping voltammetry</term><term>Ascorbic acid</term><term>Carbon black</term><term>Carbon electrode</term><term>Cyclic voltammetry</term><term>Electrochemical device</term><term>Electrochemical method</term><term>Electron transfer</term><term>Flow injection</term><term>Functionalization</term><term>Glass</term><term>Hydrogen peroxide</term><term>Indium oxide</term><term>Infrared spectrometry</term><term>Nanoparticle</term><term>Performance evaluation</term><term>Redox system</term><term>Reproducibility</term><term>Scanning electron microscopy</term><term>Square wave</term><term>Thin layer electrode</term><term>Tin oxide</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Electrode carbone</term><term>Noir carbone</term><term>Nanoparticule</term><term>Electrode couche mince</term><term>Oxyde d'indium</term><term>Oxyde d'étain</term><term>Verre</term><term>Fonctionnalisation</term><term>Microscopie électronique balayage</term><term>Spectrométrie IR</term><term>Voltammétrie cyclique</term><term>Transfert électron</term><term>Système redox</term><term>Acétonitrile</term><term>Méthode électrochimique</term><term>Evaluation performance</term><term>Acide ascorbique</term><term>Voltammétrie redissolution anodique</term><term>Onde carrée</term><term>Milieu acide</term><term>Ampérométrie</term><term>Peroxyde d'hydrogène</term><term>Injection en écoulement</term><term>Reproductibilité</term><term>Dispositif électrochimique</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Verre</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A new type of carbon film electrode, composed of a thin layer of tightly packed carbon black (CB) nanoparticles deposited onto a gelatin-covered indium tin oxide/glass support using the surface-induced deposition (SID) approach, is presented. Some parameters of the novel SID method were optimized and the surface image and functionalization of the investigated carbon black film electrode (CBFE) was inspected by employing scanning electron microscopy and infrared spectroscopy. A cyclic voltammetry (CV) study was conducted in which the electron-transfer kinetics and CBFE interfacial characteristics were evaluated employing several selected reference redox systems, such as [Ru(NH<sub>3</sub>)<sub>61</sub><sup>3+/2+</sup>, [Fe(CN)<sub>6</sub>]<sup>3-/4-</sup> and Fe<sup>3+/2+</sup> in aqueous, and ferrocene/ferrocenium in acetonitrile media. CV recordings were also performed in order to compare the electrochemical behavior of the CBFE with that of some well-known and established bare carbon-based electrodes. In order to confirm the validity of the CB film preparation method, the electroanalytical performance of the proposed CBFE was examined by carrying out linear sweep voltammetry of ascorbic acid (AA), anodic stripping square-wave voltammetry ofCu(II) in acidic medium, and amperometric measurements of hydrogen peroxide under flow injection conditions. The sensing characteristics of the novel carbon film electrode, demonstrated in this preliminary study, comprise: (i) a wide working potential window ranging from +1.0 to -1.3V (depending on the solution pH), (ii) a wide applicable pH range (at least from 2 to 12), (iii) low voltammetric background (<5 μA cm<sup>-2</sup>),(iv) a satisfactory linear voltammetric and amperometric response (r<sup>2</sup> > 0.99)to various analytes, (v) good reproducibility (for example, r.s.d. of 2% in amperometric detection of H<sub>2</sub>O<sub>2</sub> and r.s.d. of 8.5% for electrode-to-electrode CV runs), and (vi) stable and fast current response (at least 100 CV runs with negligible change in CV response). The main advantages of the proposed CBFE originate from the unique CB film formation procedure that enables fast, simple, inexpensive and non-toxic CBFE preparation, which can find application in advanced electrochemical devices and is suitable for mass production.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0003-2670</s0></fA01><fA02 i1="01"><s0>ACACAM</s0></fA02><fA03 i2="1"><s0>Anal. chim. acta</s0></fA03><fA05><s2>628</s2></fA05><fA06><s2>2</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Carbon black nanoparticles film electrode prepared by using substrate-induced deposition approach</s1></fA08><fA11 i1="01" i2="1"><s1>IRENA GRABEC SUEGL</s1></fA11><fA11 i1="02" i2="1"><s1>BELE (Marjan)</s1></fA11><fA11 i1="03" i2="1"><s1>OGOREUC (Bozidar)</s1></fA11><fA14 i1="01"><s1>National Institute of Chemistry, P.O. Box 660</s1><s2>1001 Ljubljana</s2><s3>SVN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></fA14><fA20><s1>173-180</s1></fA20><fA21><s1>2008</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>3950</s2><s5>354000185746740060</s5></fA43><fA44><s0>0000</s0><s1>© 2009 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>47 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>09-0013575</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Analytica chimica acta</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>A new type of carbon film electrode, composed of a thin layer of tightly packed carbon black (CB) nanoparticles deposited onto a gelatin-covered indium tin oxide/glass support using the surface-induced deposition (SID) approach, is presented. Some parameters of the novel SID method were optimized and the surface image and functionalization of the investigated carbon black film electrode (CBFE) was inspected by employing scanning electron microscopy and infrared spectroscopy. A cyclic voltammetry (CV) study was conducted in which the electron-transfer kinetics and CBFE interfacial characteristics were evaluated employing several selected reference redox systems, such as [Ru(NH<sub>3</sub>)<sub>61</sub><sup>3+/2+</sup>, [Fe(CN)<sub>6</sub>]<sup>3-/4-</sup> and Fe<sup>3+/2+</sup> in aqueous, and ferrocene/ferrocenium in acetonitrile media. CV recordings were also performed in order to compare the electrochemical behavior of the CBFE with that of some well-known and established bare carbon-based electrodes. In order to confirm the validity of the CB film preparation method, the electroanalytical performance of the proposed CBFE was examined by carrying out linear sweep voltammetry of ascorbic acid (AA), anodic stripping square-wave voltammetry ofCu(II) in acidic medium, and amperometric measurements of hydrogen peroxide under flow injection conditions. The sensing characteristics of the novel carbon film electrode, demonstrated in this preliminary study, comprise: (i) a wide working potential window ranging from +1.0 to -1.3V (depending on the solution pH), (ii) a wide applicable pH range (at least from 2 to 12), (iii) low voltammetric background (<5 μA cm<sup>-2</sup>),(iv) a satisfactory linear voltammetric and amperometric response (r<sup>2</sup> > 0.99)to various analytes, (v) good reproducibility (for example, r.s.d. of 2% in amperometric detection of H<sub>2</sub>O<sub>2</sub> and r.s.d. of 8.5% for electrode-to-electrode CV runs), and (vi) stable and fast current response (at least 100 CV runs with negligible change in CV response). The main advantages of the proposed CBFE originate from the unique CB film formation procedure that enables fast, simple, inexpensive and non-toxic CBFE preparation, which can find application in advanced electrochemical devices and is suitable for mass production.</s0></fC01><fC02 i1="01" i2="X"><s0>001C04C</s0></fC02><fC02 i1="02" i2="X"><s0>001C04E</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Electrode carbone</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Carbon electrode</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Electrodo carbono</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Noir carbone</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Carbon black</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Carbón negro</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Nanoparticule</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Nanoparticle</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Nanopartícula</s0><s5>03</s5></fC03><fC03 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